Bis{μ-2-[(2-oxidobenzylidene)aminomethyl]phenolato-κ3 O,N,O′}bis[(pyridine-κN)zinc(II)]
نویسندگان
چکیده
In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl-idene)amino-meth-yl]phenolate (L) ligands and one pyridine (py) mol-ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a tridentate ligand and provides a phenolate oxygen bridge which links the two Zn(II) atoms. The ZnL(py) units are linked by π-π inter-actions between adjacent pyridine mol-ecules, with a centroid-centroid distance of 3.724 Å, resulting in a two-dimensional structure.
منابع مشابه
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